Unit 4 Acid-Base and Solubility Equilibria

Introduction

“Acid”, “alkaline”, and “pH” are words often used to market everyday merchandises like bottled water and personal care products.  Here, we explore what these words mean and elaborate on the reactions between acids and bases in aqueous solution.  Acid-base reactions are also involved in the solubility of ionic compounds.  For example, the crusty buildup of minerals around a faucet can be difficult to scrub away but adding some vinegar, an acid, can dissolve away the minerals.  The concepts we learned in Unit 3, predicting the shift in equilibria and calculations using ICE tables, are applied here in the context of acid-base chemistry and low solubility ionic compounds.

Unit Learning Objectives

  • Define acids and bases.
  • Rank acids and bases by strength.
  • Calculate a solution’s pH, pOH, hydronium ion concentration, and hydroxide ion concentration.
  • Analyze acid-base titration data to determine the properties of a sample of acid or base.
  • Calculate the concentration of species and the solubility of low-solubility ionic compounds.
  • Explain how the solubility of ionic compounds is affected by the common ion effect and the addition of acid.

Unit 4 Sections

4.1 Definitions of Acids and Bases

4.2 pH Calculations and Acid-Base Strength

4.3 Polyprotic Acids and Bases

4.4 Acid-Base Reactions and Buffer Solutions

4.5 Acid-Base Titrations

4.6 Solutions of Sparingly Soluble Ionic Compounds

Each section has a reading portion, self-check question, and a set of practice exercises with solutions.  This course has a strong emphasis on solving problems by applying concepts from the reading portions.  Thus, working through the self-check questions and practice exercises is important for learning how to apply concepts in chemistry. The supplementary resources and supplementary activities within the sections are not for marks but provide alternative perspectives to enhance understanding of the course material.

Unit 4 Assignment (on Moodle)

The Unit 4 Assignment includes concepts from all the sections of the unit.  There may be a mix of written response and multiple-choice questions.  The assignment is worth 11% of the course grade.

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